The Mechanism of Room-Temperature Ionic-Liquid-Based Electrochemical CO2 Reduction: A Review
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چکیده
منابع مشابه
The Mechanism of Room-Temperature Ionic-Liquid-Based Electrochemical CO₂ Reduction: A Review.
Electrochemical CO₂ conversion technology is becoming indispensable in the development of a sustainable carbon-based economy. While various types of electrocatalytic systems have been designed, those based on room-temperature ionic liquids (RTILs) have attracted considerable attention because of their high efficiencies and selectivities. Furthermore, it should be possible to develop more advanc...
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R3 R2 There is good evidence that the first room-temperature ionic liquid or RTIL was identified and characterized by Walden in 1914, who examined the electrical conductivity of ethylammonium nitrate.1 Thus, it would not be an exaggeration to say that the very beginnings of electrochemistry involved room-temperature ionic liquids! Although once considered to be a curious subset of the general c...
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Several imidazolium-based ionic liquids significantly enhance the activity of MoO2 for electrochemical reduction of CO2. The overpotential of CO2 reduction is as low as 40 mV. The ionic liquids act as both electrolytes and co-catalysts, which not only leads to lower overpotentials, but also alters the product selectivity.
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The kinetics and mechanism of the proton reduction reaction in the room temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C(2)mim][NTf(2)]) was studied at gold, molybdenum, nickel, titanium and platinum electrodes. Significant differences in electrochemical rate constants were observed between the different metals and with the corresponding processes in aq...
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Yong-Hui Tian, T-1; George S. Goff, Wolfgang H. Runde, C-IIAC; Enrique R. Batista, T-1 Room-temperature ionic liquids (RTIL) are regarded as green solvents due to their low volatility, low flammability, and thermal stability. RTILs exhibit wide electrochemical windows, and they show potential as media for a variety of electroplating processes. Therefore, understanding the factors dominating the...
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ژورنال
عنوان ژورنال: Molecules
سال: 2017
ISSN: 1420-3049
DOI: 10.3390/molecules22040536